Animal Use Strategies in the Longshan Mountain Region of Northern China during the First Millennium BC: A Zooarchaeological Analysis of Yucun.

The first millennium BC saw the expansion of the Western Zhou dynasty in its northwestern frontier, alongside the rise and development of the Qin State in the Longshan Mountain region of northern China. Exploring the subsistence practices of these communities is crucial to gaining a better understanding of the social, cultural, and political landscape in this region at the time. While much of the research to date has focused on the Qin people, the subsistence practices of the Zhou people remain poorly understood. In this study, we analyzed animal remains from Yucun, a large settlement site associated with the Zhou people, located to the east of the Longshan Mountain. These animal remains were recovered in the excavation seasons of 2018-2020. Our results show that pigs, dogs, cattle, caprines, and horses, which were the major domestic animals at Yucun, accounted for over 90.8% of the animal remains examined in terms of the number of identified specimens (NISP) and 72.8% in terms of the minimum number of individuals (MNI), with cattle and caprines playing dominant roles. In terms of the taxonomic composition and the mortality profiles of pigs, caprines, and cattle, Yucun shared similarities with Maojiaping and Xishan, two contemporaneous Qin cultural sites located to the west of the Longshan Mountain, and differ from other farming societies in the middle and lower reaches of the Yellow River valley. Considering the cultural attributes and topographic conditions of these various sites, these findings imply that environmental conditions may have played a more significant role than cultural factors in shaping the animal-related subsistence practices in northern China during the first millennium BC.

Design of Ti-Pt Co-doped α-Fe2O3 photoanodes for enhanced performance of photoelectrochemical water splitting.

This study demonstrates Ti and Pt co-doping can synergistically improve the PEC performance of the α-Fe2O3 photoanode. By varying the doping methods, the sample with in-situ Ti ex-situ Pt doping (Tii-Pte) exhibits the best performance. It demonstrates that Ti doping in bulk facilities charge separation and Pt doping on the surface further accelerates charge transfer. In contrast, Ti doping on the surface inhibits charge separation, and Pt doping in bulk hinders charge separation and transfer. HCl treatment is used to minimize the onset potential further, while it is favorable for the ex-situ doped α-Fe2O3, which is more efficient on Tie than the Pte-doped ones. On the ex-situ Ti-doped α-Fe2O3 after HCl treatment, anatase TiO2 is probed, suggesting that Ti-O bonds accumulate when Fe-O bonds are partly removed, which enhances the charge transfer in surface states. Unfortunately, HCl treatment also induces lattice defects that are adverse to charge transport, inhibiting the performance of in-situ doped α-Fe2O3 and excessively treated ex-situ doped ones. Coupled with methanol solvothermal treatment and NiOOH/FeOOH cocatalysts loading, the optimized Ti-Pt/Fe2O3 photoanode exhibits an impressive photocurrent density of 2.81 mA cm-2 at 1.23 V vs. RHE and a low onset potential of 0.60 V vs. RHE.

Enabling high low-bias performance of Fe2O3 photoanode for photoelectrochemical water splitting.

Fe2O3 is a promising photoanode material used for photoelectrochemical water splitting due to its narrow bandgap and excellent stability in solution. However, because the nanorods shrink and coalesce when annealed under high temperatures, the charge separation and injection efficiencies are suppressed in the conventional nanocoral Fe2O3, resulting in its high bias potential and low photocurrent density. Herein, by improving the radial growth of FeOOH precursor, highly dispersed Fe2O3 nanorods could be prepared. It enabled them to have sufficient light-harvesting and short charge transport distance, high light absorption and charge separation/injection efficiencies, increased photocurrent density and reduced onset potential Von. The optimized Fe2O3 photoanodes obtained a remarkable low-bias photocurrent density of 0.84 mA cm-2 at 1.0 V versus reversible hydrogen electrode (vs. RHE). It was further improved to 1.36 mA cm-2 at 1.0 V vs. RHE with the Von reduced to 0.50 V vs. RHE when post-treated with a solvothermal method and loaded with NiOOH/FeOOH cocatalysts. The applied bias photo-to-current conversion efficiency was maximized to 0.45% at 0.84 V vs. RHE.